Paul,
Yes, two ways:
1. If you follow the book plans exactly, then as you point out those %s are calculated for you.
2. In TrainingPeaks, go to the Dashboard, choose Charts Library on the left side, then choose Time in HR Zones, Time in Power Zones, or Time in Pace Zones. Zones 1-2 are 80/20 Zones 1-2, and Zones 3-7 are Zones X-5 (because TrainingPeaks does not use Zone names, just numbers, so Zone X becomes Zone 3 in that chart, etc.)
This chart won’t work well at all if you are using HR, because HR must “pass though” every zone on the ascent and decent to/from the zone. For example, when you start a Zone 4 interval from Zone 1, your HR must pass through Zone 1, to 2, to X to 3, to Y to 4. What should be 2 minutes in Zone 4 ends up being one minutes, because the other minute was spent in the other zones on the way up. However, changes to Pace and Power are relatively instant.
David